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![]() There are some reasons, this URL supplies some of them. Especially note the repair risks and the liquid styrene risks http://www.redrockstore.com/resin.htm A short reprint of the major points follows, but a review of the total article suggested Epoxy resin is known in the marine industry for its incredible toughness and bonding strength. Quality epoxy resins stick to other materials with 2,000-p.s.i. vs. only 500-p.s.i. for vinylester resins and even less for polyesters. In areas that must be able to flex and strain WITH the fibers without micro-fracturing, epoxy resins offer much greater capability. Cured epoxy tends to be very resistant to moisture absorption. Epoxy resin will bond dissimilar or already-cured materials which makes repair work that is very reliable and strong. Epoxy actually bonds to all sorts of fibers very well and also offers excellent results in repair-ability when it is used to bond two different materials together. Initally, epoxy resin is much more difficult to work with and requires additional skill by the technicians who handle it. Vinylester resins are stronger than polyester resins and cheaper than epoxy resins. Vinylester resins utilize a polyester resin type of cross-linking molecules in the bonding process. Vinylester is a hybrid form of polyester resin which has been toughened with epoxy molecules within the main moleculer structure. Vinyester resins offer better resistance to moisture absorption than polyester resins but it's downside is in the use of liquid styrene to thin it out (not good to breath that stuff) and its sensitivity to atmospheric moisture and temperature. Sometimes it won't cure if the atmospheric conditions are not right. It also has difficulty in bonding dissimilar and already-cured materials. It is not unusual for repair patches on vinylester resin canoes to delaminate or peel off. As vinylester resin ages, it becomes a different resin (due to it's continual curing as it ages) so new vinylester resin sometimes resists bonding to your older canoe, or will bond and then later peel off at a bad time. It is also known that vinylester resins bond very well to fiberglass, but offer a poor bond to kevlar and carbon fibers due to the nature of those two more exotic fibers. Due to the touchy nature of vinylester resin, careful surface preparation is necessary if reasonable adhesion is desired for any repair work. |
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