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#31
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On Tue, 31 Jan 2006 16:20:43 -0500, "Jeff Shirton"
wrote: "B A R R Y" wrote in message .. . Don't believe you have much of a case for CO 2 poisoning. It is CO that is the poison!!! Apparently you never saw Apollo 13. I think what he's trying to imply is that CO poisons, CO2 simply displaces breathable air. Carbon monoxide is poisonous. Carbon dioxide is poisonous. Indeed, the distinction you are trying to make doesn't apply, since CO "simply displaces breathable air" in hemoglobin. Both can eventually kill you, but in different ways. Yes, by *poisoning* you. No, CO2 does not poison you. Like the pillow over a head/face it can cut off the air, but it is not a poison. It only mechanically prevents you from breathing air with O2 in it. Remove the CO2 and you can breath just fine...if you can still breathe. Remove the CO and you still need treatment as the blood still will not cary O2. A poison works chemically on the body in one way or another. Fresh air and exercise are good for refreshing after CO2, but exercise can kill after CO exposure. Roger Halstead (K8RI & ARRL life member) (N833R, S# CD-2 Worlds oldest Debonair) www.rogerhalstead.com |
#32
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![]() "T o d d P a t t i s t" wrote in message ... "Marc J. Zeitlin" wrote: ..... An excess of CO2 will not kill you. Actually, Todd, that's not true. You're right, I was wrong. I was thinking of nitrogen excluding oxygen (been playing with lots of liquid nitrogen recently and had N2 on my mind. -- T o d d P a t t i s t (Remove DONTSPAMME from address to email reply.) I think nitrogen and carbon dioxide are both heavier than air ( that is, they will pool in low areas) A sufficient excess of either can suffocate you. You can wind up drowning without getting wet. As a matter of fact, I saw a cable channel episode recently describing the loss of a few buffalo in a small valley in Yellowstone Park from such an emission near one of the active geyser areas. That incident probably involved a mix of volcanic gases rather than just CO2 but no one knows for sure, since it was a transient unmonitored event. Harold Burton |
#33
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The molecular weight of N2 is 28 compared to 32 for O2 so pure N2 is
slightly lighter than air, but not enough to make a difference. CO2 (mw=44) is significantly heavier than air and can pool in low lying areas. The bigger problem is, if a large amount of N2 (or CO2) is rapidly released in an open area, it will displace the air and reduce the amount of oxygen in that area and cause suffocation. Releasing N2 in a sealed space will simply increase the pressure in the room and cause no particular breathing problems because the room will still have enough oxygen in it to breath. You won't have a problem until the pressure gets high enough for the toxic effects of N2 to show up (nitrogen narcosis). This takes several atmospheres of pressure. Releasing CO2 in a sealed space will start causing breathing problems as soon as the CO2 pressure in the room reaches about 3/4 psi, even though the same amount of oxygen is available for breathing. A CO2 partial pressure of more than 1 1/2 psi is considered lethal. kd5sak wrote: I think nitrogen and carbon dioxide are both heavier than air ( that is, they will pool in low areas) A sufficient excess of either can suffocate you. You can wind up drowning without getting wet. As a matter of fact, I saw a cable channel episode recently describing the loss of a few buffalo in a small valley in Yellowstone Park from such an emission near one of the active geyser areas. That incident probably involved a mix of volcanic gases rather than just CO2 but no one knows for sure, since it was a transient unmonitored event. Harold Burton |
#34
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("kd5sak" wrote)
I think nitrogen and carbon dioxide are both heavier than air ( that is, they will pool in low areas) A sufficient excess of either can suffocate you. You can wind up drowning without getting wet. As a matter of fact, I saw a cable channel episode recently describing the loss of a few buffalo in a small valley in Yellowstone Park from such an emission near one of the active geyser areas. That incident probably involved a mix of volcanic gases rather than just CO2 but no one knows for sure, since it was a transient unmonitored event. PBS - Savage Planet: Degassing Lake Nyos http://www.pbs.org/wnet/savageplanet.../indexmid.html "Some 1,700 people living in the valley below Lake Nyos in northwestern Cameroon mysteriously died on the evening of August 26, 1986. Word of the disaster spread, and scientists arrived from around the world. What they discovered was that the crater lake, perched inside a dormant volcano, had become laden with carbon dioxide gas. This gas had suddenly bubbled out of the lake and asphyxiated nearly every living being in the surrounding valley community." Montblack |
#35
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"Roger" wrote in message
... No, CO2 does not poison you. Like the pillow over a head/face it can cut off the air, but it is not a poison. It only mechanically prevents you from breathing air with O2 in it. Actually, it does more than that. The CO2 level in your blood affects your breathing reflex, and while some elevation is what helps you know to take another breath, too much can interfere with your breathing in other ways. If anything, CO is more of a "mechanical blockage", because "all" it does is bind to the blood cells, preventing them from carrying O2. CO2 actually messes with your body's natural breathing control. I wouldn't really call either a "poison", but it seems to me that the words has been used pretty loosely by everyone involved in this thread. Nit-picking about whether either CO or CO2 seems fruitless. Pete |
#36
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Roger wrote:
On Tue, 31 Jan 2006 16:20:43 -0500, "Jeff Shirton" wrote: "B A R R Y" wrote in message ... Don't believe you have much of a case for CO 2 poisoning. It is CO that is the poison!!! Apparently you never saw Apollo 13. I think what he's trying to imply is that CO poisons, CO2 simply displaces breathable air. Carbon monoxide is poisonous. Carbon dioxide is poisonous. Indeed, the distinction you are trying to make doesn't apply, since CO "simply displaces breathable air" in hemoglobin. Both can eventually kill you, but in different ways. Yes, by *poisoning* you. No, CO2 does not poison you. Like the pillow over a head/face it can cut off the air, but it is not a poison. It only mechanically prevents you from breathing air with O2 in it. Remove the CO2 and you can breath just fine...if you can still breathe. Remove the CO and you still need treatment as the blood still will not cary O2. A poison works chemically on the body in one way or another. Fresh air and exercise are good for refreshing after CO2, but exercise can kill after CO exposure. Roger Halstead (K8RI & ARRL life member) (N833R, S# CD-2 Worlds oldest Debonair) www.rogerhalstead.com IIRC CO complexes the hemoglobin leading to a clot. The damage is not reversible but after a lot of time in fresh air the body will clear out the damaged hemoglobin. That's much different than CO2. |
#37
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"Jeff Shirton" wrote in message
If you don't believe me, simply do a Google search of "carbon dioxide" "poison", and see for yourself... OK. From that Google search: http://www-formal.stanford.edu/jmc/progress/co2.html "Carbon monoxide CO, unlike CO2, is a bad poison. ... Carbon monoxide binds very strongly to the iron in the hemoglobin in the blood. ... Because carbon monoxide binds to hemoglobin so strongly, you can be poisoned by carbon monoxide even at very low concentrations..." http://www.factmonster.com/ce6/sci/A0810371.html "It [carbon dioxide] does not burn, and under normal conditions it is stable, inert and nontoxic. ... Although it [carbon dioxide] is not a poison, it can cause death by suffocation if inhaled in large amounts." http://www.prn2.usm.my/mainsite/bull...995/nst13.html "Chemical asphyxiants - Carbon monoxide, hydrogen, cyanide, nitrites, hydrogen sulphides. ... Simple asphyxiants are physiolocigal inert. ... Victims exposed to them will suffer from lack of oxygen. Carbon dioxide and methane are classic examples of simple asphyxiant. Chemical asphyxiants, on the other hand, interfere with the body's ability to utilise oxygen, They either prevent oxygen delivery (such as carbon monoxide and hydrogen sulphide)..." There are many others saying that CO is a poison while CO2 is not. -- John T http://tknowlogy.com/TknoFlyer Reduce spam. Use Sender Policy Framework: http://spf.pobox.com ____________________ |
#38
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![]() "Bryan Martin" wrote in message oups.com... snip Releasing N2 in a sealed space will simply increase the pressure in the room and cause no particular breathing problems because the room will still have enough oxygen in it to breath. You won't have a problem until the pressure gets high enough for the toxic effects of N2 to show up (nitrogen narcosis). This takes several atmospheres of pressure. Although part of what you say is true, I disagree with the above paragraph. In particular the part insinuating that the nitrogen has to be pressurized to be toxic. I had a job related experience in which a contractor working under supplied breathing air respirator had a near fatal incident. The catalyst vessel he was working in was under nitrogen atmosphere to prevent the catalyst from going pyrophoric. There was no pressure on the vessel and the manway was open. He removed is mask to spit, then inhaled before putting it back on. Instead of passing out, he instantly went into violent convulsions and dropped the mask. Even with an attendant equipped with a radio, and a tripod, winch, and lanyard already set up and attached we only got him out of the vessel alive by the grace of God. If you can imagine trying to winch a grown man straight up 20' and pull him through a 18" manway while he flails wildly about with superhuman strength ... you can imagine the dilemma we were in. He seemingly had a sole determination to knock every ERT member off of a forty foot high vessel once we squeezed him through. By the time we got him restrained and an oxygen mask on him that he couldn't rip off... well to a man, we thought at best he would suffer brain damage. He did eventually recover but it was over a period of months. I personally know of two others, (one an ex-co-worker), who were put in the hospital by breathing nitrogen. It isn't something to mess with. I agree with those who state that CO messes with the Hemoglobin. We suffered one CO fatality when a technician went into a small analyzer shack to calibrate a mass spectrometer. One of the flow gauges to the machine had an o-ring leak. He apparently started feeling bad, and sat down in a chair. He didn't show up at lunch and the guys just thought he drove into town for dinner. When he didn't show up for afternoon break, his co-worker went looking... way to late. CO2 is a byproduct of our synthesis process and although it may not be a poison in the strictest sense, it will kill you just as dead. Joe Schneider 8437R ----== Posted via Newsfeeds.Com - Unlimited-Unrestricted-Secure Usenet News==---- http://www.newsfeeds.com The #1 Newsgroup Service in the World! 120,000+ Newsgroups ----= East and West-Coast Server Farms - Total Privacy via Encryption =---- |
#39
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Were there any chemical fumes in that tank he might have inhaled along
with the nitrogen? JJS wrote: "Bryan Martin" wrote in message oups.com... snip Releasing N2 in a sealed space will simply increase the pressure in the room and cause no particular breathing problems because the room will still have enough oxygen in it to breath. You won't have a problem until the pressure gets high enough for the toxic effects of N2 to show up (nitrogen narcosis). This takes several atmospheres of pressure. Although part of what you say is true, I disagree with the above paragraph. In particular the part insinuating that the nitrogen has to be pressurized to be toxic. I had a job related experience in which a contractor working under supplied breathing air respirator had a near fatal incident. The catalyst vessel he was working in was under nitrogen atmosphere to prevent the catalyst from going pyrophoric. There was no pressure on the vessel and the Joe Schneider 8437R |
#40
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Try searching on the terms "carbon dioxide poisoning" and
"Hypercapnia" instaid. CO2 is toxic but is nowhere near as toxic as CO. CO2 can act as a simple asphyxiant and kill by displacing oxygen or it can kill from its toxic effects. It's much more likely to kill by asphyxiation. It generally takes some unusual circumstances to encounter its toxic effects and it takes a fair amount of time for these effects to become dangerous. This is probably why it's not usually considered a poison, usually it will suffocate you long before it can poison you. CO will nearly always kill from its toxic effects rather than simple asphyxiation because there is rarely enough of it around to displace much oxygen in the atmosphere. CO2 poisoning is usually only a concern if you are breathing a canned atmosphere with plenty of oxygen but no way to get rid of the CO2. |
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