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On Sat, 11 Aug 2007 15:35:25 GMT, Larry Dighera
wrote: I would assume that the source of these Li-ion Polymer battery fires is excessive electrical current flowing through the battery either from too high a charging rate, too high a discharge rate, or a short internal (as in the case of the Sony laptop cells) or external, or being over charged. Perhaps it would be prudent to install a circuit breaker of fuse to prevent too high a current and a timer to disconnect a forgotten charger. I imagine the root of the problem is very low internal resistance which, while making them very efficient, also allows the current to "run away". Good circuit design can alleviate many of the issues, but safety if the batteries are damaged in a crash is still an issue. -Dana -- -- If replying by email, please make the obvious changes. ------------------------------------------------------------------------------- Abandon all hope, ye who PRESS ENTER here. |
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![]() "Dana M. Hague" d(dash)m(dash)hague(at)comcast(dot)net wrote in message ... On Sat, 11 Aug 2007 15:35:25 GMT, Larry Dighera wrote: I would assume that the source of these Li-ion Polymer battery fires is excessive electrical current flowing through the battery either from too high a charging rate, too high a discharge rate, or a short internal (as in the case of the Sony laptop cells) or external, or being over charged. Perhaps it would be prudent to install a circuit breaker of fuse to prevent too high a current and a timer to disconnect a forgotten charger. I imagine the root of the problem is very low internal resistance which, while making them very efficient, also allows the current to "run away". Good circuit design can alleviate many of the issues, but safety if the batteries are damaged in a crash is still an issue. -Dana -- Any battery chemistry, including lead-acid, can overheat with excess charging current - usually to the detriment of the battery and whatever it is in at the time. All can do damage if they are shorted. The problem with the first generation lithium cells was the chemistry released oxygen when overheated which combined with the flammable lithium made an incendiary bomb. The newest lithium-nanophosphate cells do not release oxygen and thus do not burn or explode although they can be damaged by overcharging. Cells made by A123 Systems, Saft, Valence and others are more than safe enough for use in aircraft or cars. They have a little less energy capacity than the old chemistry but they make up for it with fast charging and long life. They can typically manage a 20C discharge rate without harm - that's 200 amps for a 10 AH battery. Admittedly, you don't want to short that. Bill Daniels |
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On Mon, 13 Aug 2007 17:39:44 -0400, Dana M. Hague
d(dash)m(dash)hague(at)comcast(dot)net wrote in : safety if the batteries are damaged in a crash is still an issue. I would think the hazard somewhat less than gasoline. |
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Larry Dighera wrote:
On Mon, 13 Aug 2007 17:39:44 -0400, Dana M. Hague d(dash)m(dash)hague(at)comcast(dot)net wrote in : safety if the batteries are damaged in a crash is still an issue. I would think the hazard somewhat less than gasoline. The battery can produce it's own ignition source. |
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On Tue, 14 Aug 2007 08:40:29 -0500, "Gig 601XL Builder"
wrDOTgiaconaATsuddenlink.net wrote in : Larry Dighera wrote: On Mon, 13 Aug 2007 17:39:44 -0400, Dana M. Hague d(dash)m(dash)hague(at)comcast(dot)net wrote in : safety if the batteries are damaged in a crash is still an issue. I would think the hazard somewhat less than gasoline. The battery can produce it's own ignition source. You have a point. While a source of ignition (sparking wires, hot muffler?) is required to ignite post-crash gasoline fumes, it would take an un-fused short circuit or significant deformation of a battery to potentially ignite a lithium battery. Granted, if the crash occurs as a result of fuel exhaustion, there is little fire hazard, while the lithium would always be aboard. |
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Larry Dighera wrote:
On Tue, 14 Aug 2007 08:40:29 -0500, "Gig 601XL Builder" wrDOTgiaconaATsuddenlink.net wrote in : Larry Dighera wrote: On Mon, 13 Aug 2007 17:39:44 -0400, Dana M. Hague d(dash)m(dash)hague(at)comcast(dot)net wrote in : safety if the batteries are damaged in a crash is still an issue. I would think the hazard somewhat less than gasoline. The battery can produce it's own ignition source. You have a point. While a source of ignition (sparking wires, hot muffler?) is required to ignite post-crash gasoline fumes, it would take an un-fused short circuit or significant deformation of a battery to potentially ignite a lithium battery. Granted, if the crash occurs as a result of fuel exhaustion, there is little fire hazard, while the lithium would always be aboard. How much of a fire hazard would a paper battery be? http://www.energy-daily.com/reports/...per _999.html |
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On Wed, 15 Aug 2007 12:23:00 GMT, CanalBuilder
wrote in : How much of a fire hazard would a paper battery be? http://www.energy-daily.com/reports/...per _999.html That is an interesting device indeed. Given these quotes from the article: Rensselaer researchers infused this paper with aligned carbon nanotubes, which give the device its black color. The nanotubes act as electrodes and allow the storage devices to conduct electricity. The device, engineered to function as both a lithium-ion battery and a supercapacitor, can provide the long, steady power output comparable to a conventional battery, as well as a supercapacitor's quick burst of high energy. ... Along with use in small handheld electronics, the paper batteries' light weight could make them ideal for use in automobiles, aircraft, and even boats. The paper also could be molded into different shapes, such as a car door, which would enable important new engineering innovations. "Plus, because of the high paper content and lack of toxic chemicals, it's environmentally safe," Shaijumon said. ... "Plus, because of the high paper content and lack of toxic chemicals, it's environmentally safe," Shaijumon said. "It's a way to power a small device such as a pacemaker without introducing any harsh chemicals - such as the kind that are typically found in batteries - into the body," Pushparaj said. I find the article to be somewhat contradictory in its characterizing a lithium-ion battery as containing no harsh chemicals. And its claim of using carbon electrodes in a supercapacitor seem very counterintuitive for a low impedance device. It reads like an April Fools Day hoax. |
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On Aug 15, 8:18 am, Larry Dighera wrote:
On Wed, 15 Aug 2007 12:23:00 GMT, CanalBuilder wrote in : How much of a fire hazard would a paper battery be? http://www.energy-daily.com/reports/...oring_Power_In... That is an interesting device indeed. Given these quotes from the article: Rensselaer researchers infused this paper with aligned carbon nanotubes, which give the device its black color. The nanotubes act as electrodes and allow the storage devices to conduct electricity. The device, engineered to function as both a lithium-ion battery and a supercapacitor, can provide the long, steady power output comparable to a conventional battery, as well as a supercapacitor's quick burst of high energy. ... Along with use in small handheld electronics, the paper batteries' light weight could make them ideal for use in automobiles, aircraft, and even boats. The paper also could be molded into different shapes, such as a car door, which would enable important new engineering innovations. IF these can be made practical, they sound ideal for use in an airplane. They are light, and they can be shaped in just about any way to fit inside the airframe. Suppose they were integrated into the airframe and wings such that a large percentage of the airplane consisted of battery. It might be possible to get enough capacity there for a practical general aviation electric plane. |
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