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#1
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![]() FWIW, let me offer some information on gel coat. Beginning with coatings terminology – Paint – Dries when solvent vehicle evaporates. There are thousands of formulations and variations. Gel Coat – Cures during the molecular crosslinking (polymerization) process. Technically known as “unsaturated polyester gel coat”, this product is formulated as an in-mold coating for molded composites parts. With a few exceptions, almost every sailplane has been produced with in-mold gel coat, including those that are post-finished with a polyurethane “paint” as a secondary coating. Polyester Topcoat – Cures and dries. A hybrid consisting of unsaturated polyester resin formulated with a solvent vehicle. Products such as Prestec and Duratec are topcoats, not gel coat. Used for re-finishing original in-mold gel coat surfaces. Gel coat is not formulated to be thinned, except under very limited circumstances. Thinning gel coat with acetone (or other solvents) can result in permanent under-cure (incomplete polymerization) of the product. Many general practitioners believe that the solvent “flashes off” like a solvent vehicle in paint. However, what actually happens is that the solvent combines with the styrene monomer in the formulation, and all of the solvent does not evaporate during the cross-linking process. The result is a low cross-linking density… i.e. undercure. The ultimate result of undercure is poor weatherability exhibited by color change, dullness or chalking. Thinning gel coat with styrene is a prime cause of yellowing with UV exposure, as styrene has poor UV resistance. There are some additives available from gel coat manufacturers for patching, such as Patch-Aid and Speed- Patch. These consist of the gel coat base-resin, a promoter, and a wax additive for a tack-free surface cure, but even these additives can only be used up to a level of about 15% by weight. When gel coat is thinned enough to flow through something like an airbrush or a Preval applicator it is not going to reach its desired curing performance. The proper spray equipment to use with gel coat is a top feed gravity gun, or a pressure pot spray gun. With the appropriate equipment, gel coat can and should be sprayed without thinning the material. Another critical factor with polyester gel coat is that of spraying the appropriate thickness. This material is formulated to be sprayed at a thickness of between 14-24 mils (0.001”). Any wet film below about 14 mils produces enough surface evaporation to deplete the styrene crosslinking agent to the point where there is not enough monomer left to fully polymerize. Again, the problem with undercure is low gloss and poor weathering. Polyester Topcoats (Prestec, Duratec. Etc.) are formulated for limited thinning - Typically to around 15% of a specified solvent. To extract the required performance from these products it is critical to use only the solvent specified by the manufacturer and in no greater than the specified range. Temperature and initiator (catalyst) levels are also critical to a proper cure. Generally a minimum temperature of 70 degrees F is required for gel coat and topcoat. At lower temperatures the initial polymerization is slow and does not become complete even over an extended time. The material will appear and feel cured but the crosslinking density will be low. The initiator level (MEKP) is predicated on the weight of the gel coat or topcoat, not the combined weight of the material and thinning agent. There is a narrow range of acceptable initiator (catalyst) level depending on the material – For gel coat that is generally between 1.8% to 3% by weight, with polyester topcoats it’s generally 2% to 4% by weight. Note that all MEKP is not the same… there are many formulations. It is important to use the initiator specified by the manufacturer. Read the spec sheet and use the MEKP specified for the lab tests. To answer the original question – When spraying gel coat, a top feed gravity gun with passages large enough to spray straight (non-thinned) gel coat will produce maximum performance from the cured material. Polyester topcoats are inherently lower in viscosity and can be sprayed with smaller spray guns, keeping in mind that improper thinning reduces the effectiveness of the product cure. There are a lot of homegrown solutions and “we’ve always done it that way” folk-knowledge in the composites repair business (sailplanes, boats, etc.), but the technical facts are available to assist in producing high quality work. Bob |
#2
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On Nov 7, 5:18*am, RL wrote:
FWIW, let me offer some information on gel coat. Beginning with coatings terminology – Paint – Dries when solvent vehicle evaporates. There are thousands of formulations and variations. Gel Coat – Cures during the molecular crosslinking (polymerization) process. Technically known as “unsaturated polyester gel coat”, this product is formulated as an in-mold coating for molded composites parts. With a few exceptions, almost every sailplane has been produced with in-mold gel coat, including those that are post-finished with a polyurethane “paint” as a secondary coating. Polyester Topcoat – Cures and dries. A hybrid consisting of unsaturated polyester resin formulated with a solvent vehicle. Products such as Prestec and Duratec are topcoats, not gel coat. *Used for re-finishing original in-mold gel coat surfaces. Gel coat is not formulated to be thinned, except under very limited circumstances. Thinning gel coat with acetone (or other solvents) can result in permanent under-cure (incomplete polymerization) of the product. Many general practitioners believe that the solvent “flashes off” like a solvent vehicle in paint. However, what actually happens is that the solvent combines with the styrene monomer in the formulation, and all of the solvent does not evaporate during the cross-linking process. The result is a low cross-linking density… i.e. undercure. The ultimate result of undercure is poor weatherability exhibited by color change, dullness or chalking. Thinning gel coat with styrene is a prime cause of yellowing with UV exposure, as styrene has poor UV resistance. There are some additives available from gel coat manufacturers for patching, such as Patch-Aid and Speed- Patch. These consist of the gel coat base-resin, a promoter, and a wax additive for a tack-free surface cure, but even these additives can only be used up to a level of about 15% by weight. When gel coat is thinned enough to flow through something like an airbrush or a *Preval applicator it is not going to reach its desired curing performance. The proper spray equipment to use with gel coat is a top feed gravity gun, or a pressure pot spray gun. With the appropriate equipment, gel coat can and should be sprayed without thinning the material. Another critical factor with polyester gel coat is that of spraying the appropriate thickness. This material is formulated to be sprayed at a thickness of between 14-24 mils (0.001”). Any wet film below about 14 mils produces enough surface evaporation to deplete the styrene crosslinking agent to the point where there is not enough monomer left to fully polymerize. Again, the problem with undercure is low gloss and poor weathering. Polyester Topcoats (Prestec, Duratec. Etc.) are formulated for limited thinning - Typically to around 15% of a specified solvent. To extract the required performance from these products it is critical to use only the solvent specified by the manufacturer and in no greater than the specified range. Temperature and initiator (catalyst) levels are also critical to a proper cure. Generally a minimum temperature of 70 degrees F is required for gel coat and topcoat. At lower temperatures the initial polymerization is slow and does not become complete even over an extended time. The material will appear and feel cured but the crosslinking density will be low. The initiator level (MEKP) is predicated on the weight of the gel coat or topcoat, not the combined weight of the material and thinning agent. There is a narrow range of acceptable initiator (catalyst) level depending on the material – For gel coat that is generally between 1.8% to 3% by weight, with polyester topcoats it’s generally 2% to 4% by weight. Note that all MEKP is not the same… there are many formulations. It is important to use the initiator specified by the manufacturer. Read the spec sheet and use the MEKP specified for the lab tests. To answer the original question – When spraying gel coat, a top feed gravity gun with passages large enough to spray straight (non-thinned) gel coat will produce maximum performance from the cured material. Polyester topcoats are inherently lower in viscosity and can be sprayed with smaller spray guns, keeping in mind that improper thinning reduces the effectiveness of the product cure. There are a lot of homegrown solutions and “we’ve always done it that way” folk-knowledge in the composites repair business (sailplanes, boats, etc.), but the technical facts are available to assist in producing high quality work. Bob Great info Bob.....thanks! Brad |
#3
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On Wednesday, November 7, 2012 6:18:29 AM UTC-7, RL wrote:
FWIW, let me offer some information on gel coat. Beginning with coatings terminology – Paint – Dries when solvent vehicle evaporates. There are thousands of formulations and variations. Gel Coat – Cures during the molecular crosslinking (polymerization) process. Technically known as “unsaturated polyester gel coat”, this product is formulated as an in-mold coating for molded composites parts. With a few exceptions, almost every sailplane has been produced with in-mold gel coat, including those that are post-finished with a polyurethane “paint” as a secondary coating. Polyester Topcoat – Cures and dries. A hybrid consisting of unsaturated polyester resin formulated with a solvent vehicle. Products such as Prestec and Duratec are topcoats, not gel coat. Used for re-finishing original in-mold gel coat surfaces. Gel coat is not formulated to be thinned, except under very limited circumstances. Thinning gel coat with acetone (or other solvents) can result in permanent under-cure (incomplete polymerization) of the product. Many general practitioners believe that the solvent “flashes off” like a solvent vehicle in paint. However, what actually happens is that the solvent combines with the styrene monomer in the formulation, and all of the solvent does not evaporate during the cross-linking process. The result is a low cross-linking density… i.e. undercure. The ultimate result of undercure is poor weatherability exhibited by color change, dullness or chalking. Thinning gel coat with styrene is a prime cause of yellowing with UV exposure, as styrene has poor UV resistance. There are some additives available from gel coat manufacturers for patching, such as Patch-Aid and Speed- Patch. These consist of the gel coat base-resin, a promoter, and a wax additive for a tack-free surface cure, but even these additives can only be used up to a level of about 15% by weight. When gel coat is thinned enough to flow through something like an airbrush or a Preval applicator it is not going to reach its desired curing performance. The proper spray equipment to use with gel coat is a top feed gravity gun, or a pressure pot spray gun. With the appropriate equipment, gel coat can and should be sprayed without thinning the material. Another critical factor with polyester gel coat is that of spraying the appropriate thickness. This material is formulated to be sprayed at a thickness of between 14-24 mils (0.001”). Any wet film below about 14 mils produces enough surface evaporation to deplete the styrene crosslinking agent to the point where there is not enough monomer left to fully polymerize. Again, the problem with undercure is low gloss and poor weathering. Polyester Topcoats (Prestec, Duratec. Etc.) are formulated for limited thinning - Typically to around 15% of a specified solvent. To extract the required performance from these products it is critical to use only the solvent specified by the manufacturer and in no greater than the specified range. Temperature and initiator (catalyst) levels are also critical to a proper cure. Generally a minimum temperature of 70 degrees F is required for gel coat and topcoat. At lower temperatures the initial polymerization is slow and does not become complete even over an extended time. The material will appear and feel cured but the crosslinking density will be low. The initiator level (MEKP) is predicated on the weight of the gel coat or topcoat, not the combined weight of the material and thinning agent. There is a narrow range of acceptable initiator (catalyst) level depending on the material – For gel coat that is generally between 1.8% to 3% by weight, with polyester topcoats it’s generally 2% to 4% by weight. Note that all MEKP is not the same… there are many formulations. It is important to use the initiator specified by the manufacturer. Read the spec sheet and use the MEKP specified for the lab tests. To answer the original question – When spraying gel coat, a top feed gravity gun with passages large enough to spray straight (non-thinned) gel coat will produce maximum performance from the cured material. Polyester topcoats are inherently lower in viscosity and can be sprayed with smaller spray guns, keeping in mind that improper thinning reduces the effectiveness of the product cure. There are a lot of homegrown solutions and “we’ve always done it that way” folk-knowledge in the composites repair business (sailplanes, boats, etc.), but the technical facts are available to assist in producing high quality work. Bob Bob, Thanks for the info. Some of the Simtec products can be cut with a 50/50 mix of Acetone and Lacquer Thinner (Per the website). Also, for anyone using Prestec, help is just a phone call away. Same thing with many of the Eastwood products. |
#4
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A lot of info on spraying ... but ... if you are just repairing a "small scratch" then just brush it on and start sanding/polishing!!!
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#5
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On Wednesday, November 7, 2012 8:18:29 AM UTC-5, RL wrote:
FWIW, let me offer some information on gel coat. Beginning with coatings terminology – Paint – Dries when solvent vehicle evaporates. There are thousands of formulations and variations. Gel Coat – Cures during the molecular crosslinking (polymerization) process. Technically known as “unsaturated polyester gel coat”, this product is formulated as an in-mold coating for molded composites parts. With a few exceptions, almost every sailplane has been produced with in-mold gel coat, including those that are post-finished with a polyurethane “paint” as a secondary coating. Polyester Topcoat – Cures and dries. A hybrid consisting of unsaturated polyester resin formulated with a solvent vehicle. Products such as Prestec and Duratec are topcoats, not gel coat. Used for re-finishing original in-mold gel coat surfaces. I've seen others make this distinction whenever this topic comes up. BUT gel coats can also be applied as topcoats. The MGS (Scheufler) website has a nice document that explains the different methods for applying T35 in mold or as a topcoat. When applied as a topcoat "to repair small areas, the following procedure can be used: Add 10% Thinner HF to the gelcoat, mix thoroughly with 10% Hardener SF. Add an additional 10 - 30% acetone." The instructions go on to describe the spray technique which involves thin coats, leaving enough time for the solvents to "disappear" (5 to 10 minutes) followed by additional coats likewise laid wet on wet. |
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